I just caught this FedEx FX1988 flight on my radar. That’s a 75 miles straight line distance, 85 miles and 1 hr 26 min driving (with early morning light traffic). Or a 19 minute flight
They are likely just positioning flights - moving the aircraft so it’s ready for a passenger carrying service from a different airport. Either the way the schedules worked out required it or possibly an aircraft went unserviceable and a replacement was needed to fill the gap. There aren’t any passenger carrying flights between the London airports like that.